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| Acceso al texto completo restringido a Biblioteca INIA Las Brujas. Por información adicional contacte bibliolb@inia.org.uy. |
Registro completo
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Biblioteca (s) : |
INIA Las Brujas. |
Fecha : |
17/05/2022 |
Actualizado : |
17/05/2022 |
Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
Autor : |
PALLADINO, C.; MUELA, A.; TABORDA, B.; PUIGVERT, F.; PÉREZ-PARADA, A.; COLAZZO, M.; PÉREZ, C. A.; PEREYRA, S.; PAREJA, L. |
Afiliación : |
CINTIA PALLADINO, PDU Abordaje Holístico Al Impacto de Los Agroquímicos, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, 60000, Uruguay; AGUSTINA MUELA, Departamento de Química Del Litoral, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, 60000, Uruguay; BELÉN TABORDA, Departamento de Química Del Litoral, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, 60000, Uruguay; FLORENCIA PUIGVERT, Departamento de Química Del Litoral, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, 60000, Uruguay; ANDRÉS PÉREZ-PARADA, Departamento de Desarrollo Tecnológico - DDT, Centro Universitario Regional Del Este, Universidad de la República, Ruta 9 y Ruta 15, 27000, Rocha, Uruguay; MARCOS COLAZZO, Licenciatura en Análisis Alimentario, Inst. Tecnologico Regional Suroeste, Universidad Tecnologica, Calle 17, Saladero Santa Maria, 60000, Paysandu, Uruguay; CARLOS A. PÉREZ, Departamento de Protección Vegetal, Facultad de Agronomía, Universidad de la República, EEMAC, Ruta 3 km 363, Paysandu, 60000, Uruguay; SILVIA ANTONIA PEREYRA CORREA, INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay; LUCÍA PAREJA, Departamento de Química Del Litoral, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, 60000, Uruguay. |
Título : |
Application of a straightforward Mmthodology by LC-QqQ-MS/MS and GC-MS to ensure food safety of barley and wheat grain. |
Fecha de publicación : |
2022 |
Fuente / Imprenta : |
ACS Agricultural Science and Technology, 2022, Volume 2, Issue 2, Pages 371-380. doi: https://doi.org/10.1021/acsagscitech.1c00263 |
ISSN : |
2692-1952 |
DOI : |
10.1021/acsagscitech.1c00263 |
Idioma : |
Inglés |
Notas : |
Article history: Received 29 November 2021; Accepted 24 February 2022; Revised 4 February 2022; Published online 16 March 2022; Published in issue 18 April 2022.
Corresponding author: Pareja, L.; Departamento de Química Del Litoral, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, Uruguay; email:lpareja@fq.edu.uy -- |
Contenido : |
ABSTRACT. A multiclass methodology to determine deoxynivalenol, zearalenone, and 13 widely used fungicides to control the main diseases in barley and wheat crops was optimized and validated. Three QuEChERS methods were compared in terms of recovery and repeatability. The recoveries of the validated method were in the 67-128% range for the selected compounds and relative standard deviations were below 20% according to Document SANTE No. 12682/2019. The limits of quantification (LOQs) were between 10 and 100 μg kg-1. The method was applied for the analysis of barley and wheat grains obtained under production conditions. These samples contained mycotoxins and fungicide residues at concentrations below the LOQs, except for carbendazim in wheat, which exceeded the Codex maximum residue levels. The results of this study provide a fast and simple analytical tool to evaluate the primary production of these grains and to identify possible risks to human health.
© 2022 American Chemical Society. |
Palabras claves : |
Cereals; Food safety; Fungicide residues; Hyphenated chromatographic techniques; Mycotoxins. |
Thesagro : |
CEREALES. |
Asunto categoría : |
F01 Cultivo |
Marc : |
LEADER 02367naa a2200325 a 4500 001 1063147 005 2022-05-17 008 2022 bl uuuu u00u1 u #d 022 $a2692-1952 024 7 $a10.1021/acsagscitech.1c00263$2DOI 100 1 $aPALLADINO, C. 245 $aApplication of a straightforward Mmthodology by LC-QqQ-MS/MS and GC-MS to ensure food safety of barley and wheat grain.$h[electronic resource] 260 $c2022 500 $aArticle history: Received 29 November 2021; Accepted 24 February 2022; Revised 4 February 2022; Published online 16 March 2022; Published in issue 18 April 2022. Corresponding author: Pareja, L.; Departamento de Química Del Litoral, Cenur Litoral Norte, Universidad de la República, Ruta 3 km 363, Paysandu, Uruguay; email:lpareja@fq.edu.uy -- 520 $aABSTRACT. A multiclass methodology to determine deoxynivalenol, zearalenone, and 13 widely used fungicides to control the main diseases in barley and wheat crops was optimized and validated. Three QuEChERS methods were compared in terms of recovery and repeatability. The recoveries of the validated method were in the 67-128% range for the selected compounds and relative standard deviations were below 20% according to Document SANTE No. 12682/2019. The limits of quantification (LOQs) were between 10 and 100 μg kg-1. The method was applied for the analysis of barley and wheat grains obtained under production conditions. These samples contained mycotoxins and fungicide residues at concentrations below the LOQs, except for carbendazim in wheat, which exceeded the Codex maximum residue levels. The results of this study provide a fast and simple analytical tool to evaluate the primary production of these grains and to identify possible risks to human health. © 2022 American Chemical Society. 650 $aCEREALES 653 $aCereals 653 $aFood safety 653 $aFungicide residues 653 $aHyphenated chromatographic techniques 653 $aMycotoxins 700 1 $aMUELA, A. 700 1 $aTABORDA, B. 700 1 $aPUIGVERT, F. 700 1 $aPÉREZ-PARADA, A. 700 1 $aCOLAZZO, M. 700 1 $aPÉREZ, C. A. 700 1 $aPEREYRA, S. 700 1 $aPAREJA, L. 773 $tACS Agricultural Science and Technology, 2022, Volume 2, Issue 2, Pages 371-380. doi: https://doi.org/10.1021/acsagscitech.1c00263
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| Acceso al texto completo restringido a Biblioteca INIA Treinta y Tres. Por información adicional contacte bibliott@inia.org.uy. |
Registro completo
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Biblioteca (s) : |
INIA Treinta y Tres. |
Fecha actual : |
26/08/2020 |
Actualizado : |
24/06/2021 |
Tipo de producción científica : |
Artículos en Revistas Indexadas Internacionales |
Circulación / Nivel : |
Internacional - -- |
Autor : |
BALDASSINI, P.; BAGNATO, C.E.; PARUELO, J. |
Afiliación : |
PABLO BALDASSINI, IFEVA, Departamento de Métodos Cuantitativos y Sistemas de Información, Facultad de Agronomía; IFEVA, Departamento de Métodos Cuantitativos y Sistemas de Información, Facultad de Agronomía.; JOSÉ PARUELO, IFEVA, Departamento de Métodos Cuantitativos y Sistemas de Información, Facultad de Agronomía. INIA (Instituto Nacional de Investigación Agropecuaria), Uruguay. IECA, Facultad de Ciencias. Universidad de la República. Montevideo, Uruguay. |
Título : |
How may deforestation rates and political instruments affect land use patterns and Carbon emissions in the semi-arid Chaco, Argentina? |
Fecha de publicación : |
2020 |
Fuente / Imprenta : |
Land Use Policy, December 2020, Volume 99, Article number 104985. https://doi.org/10.1016/j.landusepol.2020.104985 |
DOI : |
10.1016/j.landusepol.2020.104985 |
Idioma : |
Inglés |
Notas : |
Article history: Received 3 February 2020; Received in revised form 23 July 2020; Accepted 3 August 2020. |
Contenido : |
In the last decades, dry Chaco forests experienced both intensive deforestation and land use changes. The intensification of deforestation at the national level led to the enactment of the National Forest Law (N° 26.331) in 2007. However, after its implementation, deforestation continued at high rates in explicitly protected areas (Categories I and II) in the provinces of Salta, Chaco and Santiago del Estero. In this article we estimated carbon (C) emission due to deforestation in a portion of the Argentine semi-arid Chaco (around 11 M ha) along 12 land use scenarios. A spatial model (InVEST) was used to prospectively analyze land use in the next 20 years, considering 4 levels of Forest Law compliance (denominated Current, Permissive, Partial and Strict) and 3 deforestation rates based on 2009-2015 records (denominated Expansion, Deceleration and Acceleration). We simulated the deforestation and its subsequent replacement by productive land uses (croplands, pastures and silvopastoral systems) based on a supervised land use classification for the year 2015. The C contents in different compartments (above and belowground biomass, litter and soil) were obtained from previous studies, based on a simulation model (CENTURY). The level of Forest Law compliance did not define the cleared area, except for those scenarios that considered a Strict compliance. Thus, productive land uses increased between 0.9 and 3.5 M ha after 20 years, depending on the deforestation rate. The total C emission was estimated between 51 and 169 Tg, where the burning of biomass and the decomposition of the remaining organic material represented about 96% of the emissions. Carbon changes in the upper 20 cm of the soil, represented a very low proportion of total emission. Although these estimations were conservative, given that not all sources have been considered, the study area showed a high potential contribution to the C emission at national scale. MenosIn the last decades, dry Chaco forests experienced both intensive deforestation and land use changes. The intensification of deforestation at the national level led to the enactment of the National Forest Law (N° 26.331) in 2007. However, after its implementation, deforestation continued at high rates in explicitly protected areas (Categories I and II) in the provinces of Salta, Chaco and Santiago del Estero. In this article we estimated carbon (C) emission due to deforestation in a portion of the Argentine semi-arid Chaco (around 11 M ha) along 12 land use scenarios. A spatial model (InVEST) was used to prospectively analyze land use in the next 20 years, considering 4 levels of Forest Law compliance (denominated Current, Permissive, Partial and Strict) and 3 deforestation rates based on 2009-2015 records (denominated Expansion, Deceleration and Acceleration). We simulated the deforestation and its subsequent replacement by productive land uses (croplands, pastures and silvopastoral systems) based on a supervised land use classification for the year 2015. The C contents in different compartments (above and belowground biomass, litter and soil) were obtained from previous studies, based on a simulation model (CENTURY). The level of Forest Law compliance did not define the cleared area, except for those scenarios that considered a Strict compliance. Thus, productive land uses increased between 0.9 and 3.5 M ha after 20 years, depending on the deforestation rate. The total C e... Presentar Todo |
Palabras claves : |
CARBON EMISSION; FOREST LAW; InVEST; LAND USE CHANGE; LAND USE SCENARIOS; PROTECTED AREA; REGIÓN SEMI-ARIDA; SEMI-ARID REGION. |
Thesagro : |
DESFORESTACIÓN; EMISIONES DE CARBONO. |
Asunto categoría : |
A50 Investigación agraria |
Marc : |
LEADER 03000naa a2200289 a 4500 001 1061278 005 2021-06-24 008 2020 bl uuuu u00u1 u #d 024 7 $a10.1016/j.landusepol.2020.104985$2DOI 100 1 $aBALDASSINI, P. 245 $aHow may deforestation rates and political instruments affect land use patterns and Carbon emissions in the semi-arid Chaco, Argentina?$h[electronic resource] 260 $c2020 500 $aArticle history: Received 3 February 2020; Received in revised form 23 July 2020; Accepted 3 August 2020. 520 $aIn the last decades, dry Chaco forests experienced both intensive deforestation and land use changes. The intensification of deforestation at the national level led to the enactment of the National Forest Law (N° 26.331) in 2007. However, after its implementation, deforestation continued at high rates in explicitly protected areas (Categories I and II) in the provinces of Salta, Chaco and Santiago del Estero. In this article we estimated carbon (C) emission due to deforestation in a portion of the Argentine semi-arid Chaco (around 11 M ha) along 12 land use scenarios. A spatial model (InVEST) was used to prospectively analyze land use in the next 20 years, considering 4 levels of Forest Law compliance (denominated Current, Permissive, Partial and Strict) and 3 deforestation rates based on 2009-2015 records (denominated Expansion, Deceleration and Acceleration). We simulated the deforestation and its subsequent replacement by productive land uses (croplands, pastures and silvopastoral systems) based on a supervised land use classification for the year 2015. The C contents in different compartments (above and belowground biomass, litter and soil) were obtained from previous studies, based on a simulation model (CENTURY). The level of Forest Law compliance did not define the cleared area, except for those scenarios that considered a Strict compliance. Thus, productive land uses increased between 0.9 and 3.5 M ha after 20 years, depending on the deforestation rate. The total C emission was estimated between 51 and 169 Tg, where the burning of biomass and the decomposition of the remaining organic material represented about 96% of the emissions. Carbon changes in the upper 20 cm of the soil, represented a very low proportion of total emission. Although these estimations were conservative, given that not all sources have been considered, the study area showed a high potential contribution to the C emission at national scale. 650 $aDESFORESTACIÓN 650 $aEMISIONES DE CARBONO 653 $aCARBON EMISSION 653 $aFOREST LAW 653 $aInVEST 653 $aLAND USE CHANGE 653 $aLAND USE SCENARIOS 653 $aPROTECTED AREA 653 $aREGIÓN SEMI-ARIDA 653 $aSEMI-ARID REGION 700 1 $aBAGNATO, C.E. 700 1 $aPARUELO, J. 773 $tLand Use Policy, December 2020, Volume 99, Article number 104985. https://doi.org/10.1016/j.landusepol.2020.104985
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